CE 401L – Advanced Inorganic Chemistry Laboratory

Fall 2003 – Monmouth University

 

PROFESSOR:     Dr. Robert Topper

                                Office: E-243        Phone: (732) 571-4418

                                Email: rtopper@monmouth.edu

                                Web: http://www.monmouth.edu/~rtopper

 

REQUIRED TEXT:            Synthesis and Technique in Inorganic Chemistry (3rd ed.)

                                                by G.S. Giolami, T.B. Rauchfuss, and R.J. Angelici.

CLASS MEETINGS:          T 2:30- 5:20 PM. There are 14 laboratory meetings.

OFFICE HOURS:               Th 1:00-3:00 PM, or by appointment.

PREREQUISITES: This advanced laboratory course has CE401 as a corequisite and CE 372 / CE372L as prerequisites. Students currently enrolled in CE372 and CE372L may be allowed to take this course with the instructor's permission, but only if they have completed CE241/CE241L and CE242/CE242L (Organic Chemistry I and II with Lab). Students are generally also presumed to have completed the sophomore-level CE221 and CE221L (Quantitative Analysis) courses or their equivalents.

 

LAST DATE TO WITHDRAW WITH AUTOMATIC "W": Wednesday, November 5.

 

SAFETY:  Safety goggles must be worn in the laboratory by all persons while anyone is working with hazardous chemicals in the laboratory. Safety goggles are provided. Safety glasses are not acceptable for many experiments as they do not provide full splash protection or protection from chemical vapors. However, it is generally safe to wear contact lenses under safety goggles. Sandals, or any other footwear which does not completely cover the foot, are not permitted in the laboratory. Use of a lab coat or apron and / or sturdy cotton clothes is recommended. Food and drink are not permitted in the lab.

 

You are responsible for looking up and understanding the MSDS of chemicals used in the day's experiment and summarizing their safety and handling information in your laboratory notebook before you will be allowed to start working.

 

ATTENDANCE: Attendance is generally mandatory. All experiments must be completed in order to receive a passing grade in the course. All experiments should be during the scheduled laboratory periods unless otherwise announced. Experiments may not be carried out without faculty supervision under any circumstances.

 

ORGANIZATION: There are 14 lab meetings this semester. The list of experiments to be performed is attached. The schedule may change as necessary as equipment needs and other scheduling considerations dictate. You will be informed a week in advance of each experiment which experiment will be begun the following week.

 

OBJECTIVES: Students should gain a deeper knowledge of the synthesis and characterization of inorganic compounds. They will also learn how to work collaboratively with colleagues in an industrial setting, and how to communicate their findings effectively to an employer.

 

GRADES: Grades will be based on the following considerations: your written Technical Reports (40%); your Technique, as reflected in your accuracy, precision, and the quality/yield of synthesized products (25%); your Preparation and Organization (25%); and your demonstrated professionalism as manifested in your Attendance, Effort and Collegiality (10%).  Based on these categories a point total (maximum 100) will be earned by the end of the semester. This point total will  be used to assign the final grade according to the scale below:

 

A=92, A-=88, B+=84, B=80, B-=76, C+=72, C=69, C-=66, D+=63, D=60, D-=57; F=below 57.

 

No extra assignments or projects will be accepted in order to improve your grade. I reserve the right to make a judgement call in borderline cases based on my best professional acumen.

 

Preparation/Organization will be assessed by weekly examination of your laboratory notebook (see below) and by observation. You will earn maximum credit for Attendance, Effort and Collegiality by coming to each scheduled lab period, coming on time, trying your best, and working respectfully with your instructor, the lab technician and your fellow students. If you are sick and can't come to lab, call or email before the lab starts or you will lose credit.

 

NOTEBOOK: You must have a cloth-bound notebook with pages sewn in.

 

Before beginning each day's experimentation, you must research and record a summary of the relevant safety and handling information for all of the substances you will be working with that day. If you are not prepared in this manner before each class, you will not be allowed to work that day.

 

Lab notebooks should be kept neat and organized. All data must be entered directly into the notebook using ink. If an error is made, cross out the incorrect entry and write the new entry beside or above it. Date each page of the notebook. Make sure you know how to do any calculations you will need for each day's work in advance and include them in your notebook as well.

 

STATEMENT ON ACADEMIC HONESTY: You may not use or copy material from any unattributed sources in your reports. Furthermore, you may not consult any sources which you do not attribute in your Bibliography. Both of these actions are examples of academic fraud, or plagiarism. Committing plagiarism, or conspiring with another student to commit plagiarism by allowing another student to borrow your report so that they can copy from it, will result in very serious consequences. The minimum penalty will include all authors of a report receiving a grade of zero for the report, but depending on the circumstances heavier penalties may accrue (including receiving an F in the course as well as a report to the Provost and the Judicial Board).

 

STUDENTS WHO NEED SPECIAL ACCOMODATIONS: Students with disabilities who need special accomodations for this class are encouraged to meet with the professor or the appropriate disability service provider on campus as soon as possible. In order to receive accomodations, students must be registered with the appropriate disability service provider on campus as set forth in the Student Handbook and must follow the University procedure for self-disclosure, which is stated in the University Guide to Services and Accomodations for Students with Disabilities. Students will not be afforded any special accomodations for academic work completed prior to disclosure of the disability and completion of the documentation process with the appropriate disability service office.

 

 

 

 

 

 

TECHNICAL REPORTS: After the completion of a given experiment, you must write a technical report in the same manner and format as that used by research chemists and chemical engineers in industry. The report must be written in prose and no outlines or bulleted lists are generally permitted.  The format is discussed below.

 

Each student will write his or her own technical report if the experiment is carried out by one individual. However, if an experiment is carried out with one or more partners you will usually have the option of either turning in individual reports or a joint report with both of your names, for which you will both receive the same grade. You must both contribute equally to the writing of a joint report and identify which sections were written by which student. Moreover, you are both fully responsible for ALL of the report and must review each other's work. If one partner plagiarizes part of the report, you will both be held fully responsible. Moreover, if you turn in a joint report you will both receive the same grade. Do not complain if your lab partner fails to do his or her share on a technical report.

 

 

MORE ON TECHNICAL REPORTS:

Reports must be typed (not handwritten) and the text should be submitted both electronically by email or on media (in DOC format) and in print . Technical reports should usually 1-2 pages in length, single spaced, excluding biblography, figures, graphs and tables, which should always be given as attachments. Three pages is the absolute maximum length allowed. Attachments should be numbered and an (unnumbered) list of all attachments must be given after the 1-3 page technical report and the bibliography. Quoted paragraphs are generally not acceptable as part of the content of a report. The entire report should be written using your own words.

 

Technical reports and synthesized products are generally due 1  week after the completion of an experiment. Note that some experiments will take more than 1 week.

 

Grammar and spelling DO count as part of your technical report grade. Also, make sure there are no typgrphcall errrs unles yew wantt two bee yelld att (and have your grade lowered).

 

Always start out with a one-paragraph summary of the experiment (what was done and what its purpose was and what the result was). If a synthesis is reported, give the experimental yield and, if possible, a very brief description of any other outcomes. All in a single paragraph! Make sure to consult an ACS journal article for an example before turning in your first report.

 

You will need to include a brief discussion of the relevant reactions studied or carried. Balanced equations for all relevant reactions will typically be part of this discussion.

 

The procedure should then be briefly (but completely) described. If you did not deviate in any way from a procedure described in the text or in an article or handout, you should simply say something along the lines of "The procedure described in Giolami et al. was followed without modifications." If you do this, make sure to include the full reference (the ACS style is recommended) in a Bibliography attachment. If any changes are made to written procedures they must be documented here. This is also an appropriate place to describe any and all errors and how they were handled ("As the crystals formed were noticeably contaminated with impurities, at the suggestion of the instructor the sample was recrystallized at the suggestion of the instructor using a minimum of solvent."

 

A concluding paragraph describing your conclusions and your future recommendations is always mandatory. The outcome of the experiment should be summarized, and recommendations made for future work. You must make a recommendation as to whether this experiment be used the next time this course is taught, or whether it should be replaced by another experiment. Useful suggestions as to how to improve the procedure are generally good things to do, as are ideas for other experiments to follow up on (or replace) the investigation you are describing.

                                               

Attachments will include the following:

1. Bibliography (if necessary)

2. List of Attachments.

3,4,5.,….(all supplementary data, figures, diagrams, plots, data analysis, etc.)

 

Documenting Data, Figures, and Data Analysis - The data must be presented in neat, well-organized tables. Tables must have a title which clearly explains the contents of the table. Units must be clear and symbols must be defined either in the text or in a table caption. Figures must also have a title. Units must be clear. A figure caption may also be necessary to explain the figure's contents or meaning. All calculations must be fully explained in an attachment. A sample calculation should be given to illustrate a complicated data analysis.